Automatic form detection and filling
You can have 1Password automatically save a new Login for the form that’s open in your browser, and you can have 1Password automatically submit a login form right after it fills the fields—those options are in the 1Password dialog box you see when you click the 1Password button in the browser’s toolbar.
There’s not an “autofill” option, though. You have to take an action to get 1Password to fill the fields on a login form.
There are a couple of ways to trigger a “fill”:
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Click the 1Password button in your browser’s toolbar, click the Go & Fill Logins button, and choose the Login item for the login form you want 1Password to display, fill, and (optionally) submit.
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In a browser, go to a web site for which you already have a Login saved, and press Ctrl+\; 1Password will fill the fields and (optionally) submit the form.